云南墨江金厂矿床金镍赋存状态及成因关系探讨     

周凯  张洪瑞  柴鹏  张慧超  程先锋  杨澍 《矿床地质》2020,39(1):97-110

墨江金厂金镍矿床位于哀牢山造山带中段,九甲—安定大断裂上盘,是西南三江成矿带内一个独特的金镍矿床。本文在详细野外地质调查基础上,通过显微镜下观察、扫描电镜和能谱分析,结合矿石微量元素分析,对矿石中金、镍赋存状态及成因关系进行了研究。结果显示,金赋存形式主要有可见金和不可见金。可见金又可分为粒间金和包体金;不可见金是以Au~+赋存于硫锑铜银矿、黄铁矿中。镍赋存状态有两种:一是以独立矿物,如辉砷镍矿、锑硫镍矿等存在;二是以离子态赋存于黄铁矿、硫锑铜银矿中。矿石结构构造、矿物共生组合及微量元素含量等显示,金和镍为同期热液成矿,金来自岩浆热液系统远端的低温热液,镍是含金低温热液流经超基性岩体时萃取而来。成矿过程可分为早期富硅质热液和晚期富钙质热液两个阶段,成矿是在幕式构造活动下多期流体运移和沉淀的结果。  相似文献   

西藏冈底斯岩带曲水杂岩体锆石LA-ICP-MS U-Pb年龄及其地质意义     

次琼  永忠拉达  阿旺旦增  次仁吉 《沉积与特提斯地质》2020,40(2):116-128

曲水杂岩体位于冈底斯构造-岩浆岩带东段南缘,其岩浆活动与雅鲁藏布江新特提斯洋壳向北俯冲、消减以及印度与欧亚板块碰撞息息相关。本文以曲水县-昌果乡广泛分布的中酸性花岗岩体为研究对象,进行了系统的LA-ICP-MS锆石U-Pb年代学和岩石地球化学研究。结果表明,曲水杂岩体由3期时代和规模不同的花岗质岩体构成,其LA-ICP-MS锆石U-Pb年龄分别为95.2±1.0～88.5±1.0Ma、65.2±0.6Ma和48.5±0.5～43.3±0.7Ma;岩石地球化学研究表明,晚白垩世和古新世花岗岩以中性-中酸性为主,属钙碱性系列,具中铝特征,A/CNK比值小于1.1,属于I型花岗岩,是玄武质下地壳部分熔融产物,指示其形成于特提斯洋壳俯冲过程的岛弧构造环境。始新世花岗岩以高钾钙碱性系列为主,并出现钾玄岩系列,具偏铝-过铝质特征,指示岩浆上侵过程中遭受了不同程度的地壳物质混染,其形成于印度-欧亚板块强烈碰撞的构造环境。  相似文献   

水资源约束下的河西走廊城市经济脆弱性时空演变及其影响因素     

张戬  陈佳  黄馨  王子侨 《中国沙漠》2019,39(1):203-211

城市经济脆弱性作为当前脆弱性研究中的重要领域，为人-地系统耦合研究提供了新的视角，并为城市可持续健康发展提供有益的决策支持和管理方法。依据城市经济脆弱性内涵，基于暴露度、敏感性、适应能力构建了城市经济脆弱性评价指标体系，运用熵权TOPSIS法评价河西走廊地区及区域内五市的城市经济脆弱性，并采用障碍度模型识别影响区域城市经济脆弱性变化的因素。结果显示：（1）2006—2015年，河西走廊地区城市经济脆弱性呈现出先曲折下降（2006—2011年）再波动上升趋势（2012—2015年）；（2）河西走廊地区的城市经济脆弱性具有明显的空间特征，经历了东西高、中部低到整体较高的演变过程；（3）阻碍河西走廊地区城市经济脆弱性降低的障碍因子由适应能力逐步转变为暴露度。针对河西走廊地区各市主要障碍因子，提出针对性优化措施。  相似文献   

Extraction of Lithium from Salt Lake Brine using N523-TBP Mixture System   总被引：1，自引：1，他引：0       下载免费PDF全文

SHI Dong  LI Li-juan  LI Jin-feng  JI Lian-min  SONG Fu-gen  PENG Xiao-wu  ZHANG Li-cheng  ZHANG Yu-ze  LI Hui-fang  SONG Xue-xue  NIE Feng  ZENG Zhong-min  LIU Zhi-qi  GUO Fan 《盐湖研究》2019,27(2):95-110

In this work,problems encountered by tri-butyl phosphate( TBP) in the industrialization of lithium extraction from salt lake brine were discussed in detail. The behavior of N,N-bi-( 2-ethylhexyl) acetamide( N523) during lithium extraction was investigated,and its disadvantages were analyzed in the view of practical application. An N523-TBP mixture extraction system was proposed to alleviate or avoid the defects that N523 and TBP met when they were used separately. The optimal composition of this mixture extraction system was determined to be 20% N523-30% TBP-50% kerosene.The effects of brine acidity,Fe/Li molarity ratio,phase ratio and chloride ion concentration on lithium extraction efficiency were discussed. The operation conditions in single-stage extraction were optimized as brine acidity = 0. 05 mol/L,Fe/Li molarity ratio = 1. 3,and phase ratio = 2. The high concentration of chloride ions in brine was beneficial for the extraction of lithium. The structure of the extracted complex was proposed as( LiFeCl_4·n N523·m TBP)·( 2-n) N523·( 2-m) TBP( m + n = 2) by chemical analysis and slope-fitting methods. The extraction thermodynamic functions were calculated preliminarily,and the results suggested that the extraction process was an exothermic( ΔH 0) and spontaneous( ΔG 0) reaction,and the degree of disorder increased( ΔS 0) during the extraction process. This work will give some guidance to the lithium industry of Qinghai in both the fundamental theory and practical application.  相似文献   

Fully coupled hydraulic fracture simulation using the improved element partition method     

Shujun Peng  Zhennan Zhang  Jianye Mou  Bing Zhao  Zhiyuan Liu  Jiading Wang 《国际地质力学数值与分析法杂志》2019,43(1):441-460

The improved element partition method (IEPM) is a newly developed fracture simulation approach. IEPM allows a fracture to run across an element without introducing extra degrees of freedom. It can also simulate any number of fractures in a prescribed mesh without remeshing. In this study, the IEPM is extended to hydraulic fracture simulation. First, the seepage and volumetric storage matrix of a cracked element are derived using virtual nodes (the intersection points of a crack with element edges). Subsequently, the fully coupled hydromechanical equation is derived for this cracked element. To eliminate the extra degrees of freedom (virtual nodal quantities), the water pressure and displacement of the virtual nodes are associated with their adjacent nodes through least squares interpolation. Finally, the fully coupled equation in terms of nodal quantities is obtained. The verification cases validate the method. By using this method, the field-scale hydraulic fracturing process is well simulated. The proposed approach is simple and efficient for field-scale hydraulic fracture simulation.  相似文献   

Quantitative prediction of discrete element models on complex loading paths     

Luc Sibille  Pascal Villard  Félix Darve  Rodaina Aboul Hosn 《国际地质力学数值与分析法杂志》2019,43(5):858-887

The ability of discrete element models to describe quantitatively (and not only qualitatively) the constitutive behaviour of a dense sand is assessed in this paper. Two kinds of 3D discrete models are considered. Both consider spheres as elementary particles. Nevertheless, the first model implements a contact law with rolling resistance whereas the second takes into account clumps made of two spheres. The discrete models are calibrated and validated from mechanical tests performed on a dense Hostun sand with a true triaxial apparatus. The calibration is carried out from axisymmetric drained compression tests, while the validation is discussed from monotonic and cyclic stress proportional loading paths and from a circular stress path in the deviatoric stress plane. The quality of the predictions of the discrete models are evaluated by comparison with the predictions given with advanced phenomenological constitutive relations, mainly an incrementally non-linear relation. Predictions given by the discrete models are remarkable, particularly when it is put in perspective with respect to the very few number of mechanical tests required for their calibration. However, these results and conclusions were reached in enabling conditions, and some limitations of such discrete models should be kept in mind.  相似文献   

内蒙古狼山地区早二叠世花岗闪长岩的年代学、地球化学特征及其构造背景     

田健  滕学建  刘洋  滕飞  郭硕  何鹏  王文龙 《中国地质》2020,47(3):767-781

内蒙古狼山山脉西侧分布有大面积的晚古生代岩浆岩,其时代集中在早石炭世—晚二叠世,不同时代岩浆岩岩石组合对于认识狼山地区晚古生代构造背景具有重要的意义。文章通过岩石学、岩相学、地球化学及Hf同位素等方法,对狼山地区查干乃呼都格一带花岗闪长岩体进行了研究。该岩体岩性为花岗闪长岩,LA-ICP-MS锆石U-Pb年龄显示,其206Pb/238U加权平均年龄为(299±1)～(293±2) Ma。岩石暗色矿物为角闪石及黑云母,富含闪长质包体,P_2O_5含量与SiO_2含量之间显示良好的负相关性,富钠(Na_2O含量为3.45%～4.96%),高钠钾比值(Na_2O/K_2O比值为1.33～2.52),岩石地球化学特征显示花岗岩成因类型为Ⅰ型花岗岩。岩石具有负的ε_(Hf)(t)值(-6.3～-2.0)及T_(DM2)为1437～1704 Ma(平均值为1606 Ma),显示了古—中元古代古老地壳熔融的特点,ε_(Hf)(t)-t及角闪石成因图解显示源区有幔源岩浆参与。花岗岩富集大离子亲石元素Rb、K、Pb,不同程度的亏损高场强元素Nb、Ta、P、Ti,轻稀土富集,重稀土亏损,弱的负Eu异常,显示了岩浆弧的地球化学特征。结合晚石炭世—早二叠世狼山地区侵入岩岩石组合为闪长岩+石英闪长岩+花岗闪长岩(英云闪长岩),早—中二叠世大石寨组火山岩岩石组合为玄武岩+玄武安山岩+安山岩+英安岩,总体反映了陆缘弧的岩石组合;狼山地区早二叠世处于大陆边缘弧的构造背景,与华北地块北缘中东部可以对比。  相似文献   

基于钻进状态监测的智能工况识别          下载免费PDF全文

范海鹏  吴敏  曹卫华  赖旭芝  陈略峰  陆承达 《探矿工程》2020,47(4):106-113

钻进过程状态监测旨在实时描述钻进工况，判断运行性能优劣程度进行非优追溯，及时指导司钻人员调整作业操作,保证钻进过程安全、高效、稳定开展。钻进工况是钻进系统运行状态的反映，因此开展面向状态监测技术的钻进工况识别研究具有重要的理论和应用价值。本文针对钻进工况识别问题，基于状态监测数据，建立基于支持向量机的钻进工况识别模型，对钻进工况进行识别。综合工况识别结果，对钻进效率进行评估，并对影响钻进效率的因素进行讨论，寻找提升钻进效率的手段。最后，采用钻进现场实钻数据进行仿真实验,验证所提方法的可行性和有效性。  相似文献   

Sedimentary and geochemical characterization of Middle–Late Miocene formations in the Neogene Tsugaru Basin,Japan by means of DTH27‐1 well sediment analysis     

Paolo Martizzi  Shun Chiyonobu  Hiroyuki Arato 《Island Arc》2020,29(1)

Middle–Late Miocene age siliceous formations outcropping along the northwestern side of Honshu Island are considered prospective source rocks for hydrocarbons. An analysis of geophysical, sedimentological, and geochemical properties is essential to evaluate the formations' source potential, and to understand the factors that determined the accumulation and preservation of organic matter. This study investigates the Middle–Late Miocene geological record of the Tsugaru back‐arc basin, located in the western part of Aomori prefecture, through an analysis of a 200 m long portion of a core from the DTH27‐1 well; this core is composed of the diatomaceous siltstones of the Akaishi Formation and the siliceous mudstones of the Odoji Formation. Sedimentological and geophysical characterization showed that the Akaishi Formation's diatomaceous siltstones are mostly massive and bioturbated, have low magnetic susceptibility, and demonstrate moderate natural radioactivity. Although the Odoji Formation's siliceous mudstones are massive, they have exceedingly low magnetic susceptibility and high natural radioactivity. Geochemical data from a Rock‐Eval Pyrolysis such as total organic carbon and generative potential (S1 + S2) revealed that, in the Tsugaru area, only the Odoji Formation is a likely prospective source rock for hydrocarbons. On the other hand, T_max values indicate that both the formations are thermally immature for generating hydrocarbons. The difference between the Akaishi and Odoji Formation in the sedimentological facies, in terms of the degree of bioturbation and the organic carbon content, indicates variations in lithological properties, such as porosity and grain size; moreover, this difference indicates a variation in the paleo‐oxygenation of bottom waters, with the transition from oxygen‐deficient conditions in the Middle Miocene to the more oxygenated conditions in the Late Miocene. Both the lithological and paleo‐environmental factors possibly influenced the organic richness in the two formations.  相似文献   

多层构造油藏纵向细分计算单元对储量参数及结果的影响     

颜冠山  刘宗宾  宋洪亮  韩雪芳  王欣然 《地质与资源》2020,29(4):342-350

为满足油田中后期精细开发及后续调整挖潜的需要，亟需进行更精细的储量研究，其中最重要的一环就是纵向细分计算单元.对于多层构造油藏，纵向细分主要根据油层组内隔夹层分布特征、小层物性特征，细分到以小层或者分布特征和物性相近且纵向上连续分布的小层组合为计算单元.根据纵向细分计算单元前后储量参数选值的理论推导，结合储层的沉积展布特征，认为含油面积范围内无储层尖灭时，仅平面油层厚度差异较大的油藏平均有效厚度变小.含油面积范围内储层尖灭时，正常三角洲沉积储层的油藏各参数一般都变小；而辫状河三角洲沉积储层的油藏一般平均有效厚度变小，平均有效孔隙度和平均含油饱和度变大.这一结论可以有效指导储量评估过程中纵向细分计算单元方案划分，为同类油田的精细储量研究提供技术支撑.  相似文献